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DPPE |
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From these data, the actual oxidation state of the Pt metal with dppe and an organic group and of the Pt metal with CO and Cp ligands were calculated to be close to two and zero, respectively, though the formal oxidation state of each is one. [alpha]] resonance, which was unambiguously assigned on the basis of the coupling to the dppe phosphorus nuclei, falls at the higher end of frequencies found in other acetylide complexes, [Fe(C[equivalent to]CR)(dppe)[Cp. 6 This work (a) dppe = 1,2-bis(diphenylphosphine)ethane. |
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