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Table 5 - comparison of curatives in bromobutyl rubber Curative MBTS/ A-189 TMTD XIIR 100 100 N-550 carbon black 55 55 Paraffinic oil 10 10 Zinc oxide 3 3 Stearic acid 1 -- MBTS 1. With the exception of the FKM fluorocarbon, the VMQ silicone and the XIIR isobutyl rubber, all materials were seriously degraded; the materials most adversely affected were the natural rubbers and their close polymeric analogue, the neoprenes. HNBR shows good-to-excellent adhesion when covulcanized to: CSM (all types of curing systems); ECO (sulfur, ethylene thiourea and peroxide curing systems); NBR (peroxide curing system); and fluoroelastomer (bisphenol curing system) HNBR shows moderate adhesion when covulcanized to: ECO (diamine curing system); NBR (sulfur curing system); XIIR (sulfur and peroxide curing systems); and fluoroelastomer (peroxide curing system). |
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