Preparation of Monomer of Benzoxazine-Functional 3-Aminopropyltrimethoxysilane:
Into 250 mL round-bottom flask containing 80 mL chloroform, bisphenol-A (9.1316 g, 100.0 mmol), 3-aminopropyltrimethoxysilane (13.9661 g, 200 mmol), paraformaldehyde (5.1051 g, 400 mmol) were added.
We mixed each purified PCR product (10 [micro]L at concentrations [is greater than] 200 ng/[micro]L) with 10 [micro]L of 8 M NaSCN in 96-well plates and spotted the DNA using the Molecular Dynamics Microarray Spotter Gen II (Molecular Dynamics, Sunnyvale, CA), onto slides treated by vapor deposition of 3-aminopropyltrimethoxysilane
Bis(3-phenyl-3,4-dihydro-2H-1,3-benzoxazinyl)isopropane or Bisphenol-A as a standard benzoxazine monomer, paraformaldehyde (99%), Tetrahydrofuran (THF), aniline (99%) and 3-aminopropyltrimethoxysilane (98%) were obtained from Sigma Aldrich Co.
Furthermore, the strong absorption bands corresponding to water molecules hydrogen bonded to silanol groups at 1634 [cm.sup.-1] [7,5] and Si-C[H.sub.2] vibrations at 1260 [cm.sup.-1]  indicate 3-aminopropyltrimethoxysilane were hydrolyzed and participated in the formation of poly B-z[(OH).sub.3] network.
The MCM-41 adsorbent containing aminopropyls, N[H.sub.2]-MCM-41, was prepared by refluxing of 2.5 g MCM-41 powder in 250 mL dry toluene (>99.5%, Mallinckrodt) containing 0.4 M 3-aminopropyltrimethoxysilane
(97%, Aldrich) for 18 h.
(number 52 Ningbo Road, Shanghai, China); silver nitrate ([greater than or equal to] 99%), hydroxylamine hydrochloride ([greater than or equal to] 99%), 3-aminopropyltrimethoxysilane
(APTMS, 97%), and furazolidone (ACS grade) were obtained from Sigma-Aldrich (St.
1-Ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride (EDC), N-hydroxysuccinimide (NHS), and 3-aminopropyltrimethoxysilane
(APS) were purchased from Sigma-Aldrich (St.
Commercially available 3-aminopropyltrimethoxysilane, SA1, 2-aminoethyl-3-aminopropyltrimethoxysilane, SA2, 3-glycidoxypropyltrimethoxysilane, SA3, and poly(dimethylsiloxane) with--Si(C[H.sub.3])[.sub.2]OH end-groups ([M.sub.n] ~ 2200 g [mol.sup.-1]) were supplied by Dow Corning do Brasil (Hortolandia, SP, Brazil), while the DGEBA-based epoxy resin poly(bisphenol-A-co-epichloridrin) of low molar mass and 4,4'-diaminodiphenylmethane were purchased from Dow Chemical (Sao Paulo, Brasil) and Fluka (Sao Paulo, Brasil), respectively, and used as received.
The inorganic components were 3-aminopropyltrimethoxysilane, SA1, 2-aminoethyl-3-aminopropyltrimethoxysilane, SA2, or 3-glycidoxypropyltrimethoxysilane, SA3, and the organic components were the DGEBA-based epoxy resin poly(bisphenol-A-co-epichloridrin) or DAF.
Firstly, we decorated a layer of 3-aminopropyltrimethoxysilane
(APTMS) on clean ITO (Figure 1(a)), and then this substrate was immersed into as-prepared Ag colloid solution for decorating Ag seeds on the substrate (Figure 1(b)), followed growth of Ag nanoplates by electrochemical deposition route on the substrate directly.