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References in periodicals archive ?
To the best of our knowledge, this is the first example about the synthesis and isolation of a silver aNHC complex.
A rational explanation of the high catalytic activity of complex 14 in AAC should include the above mentioned elements together with the ability of the aNHC ligand to protect the silver (I) ion and stabilize some intermediates such as silver acetylides.
The catalytic activity in this kind of compounds is improved with the introduction of aNHC ligands avoiding side reactions and facilitating the purification of final products, such as many copper catalyzed cycloadditions.