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References in periodicals archive ?
Background solutions of CaCl2 with 0.005M were used for the preparation of working solutions having different concentrations.
The supernatant was replaced by 8 mL of background solution containing 1.0 mg/L of phenanthrene and the vials were then shaken for 24 h.
The response shown by the conductivity profiles is very similar (note that there are slight differences in the initial conductivity of the tracer and background solutions).
Twenty-five mL of Cu-free, 0.01 M NaOAc background solution was then added to the vials to initiate desorption of previously sorbed Cu.
All sorption isotherm approaches in this study were performed in duplicate and employed a background solution buffered to pH 5.0 [+ or -] 0.2 with 0.01 M NaOAc.
These workers found that Cu sorption to 2 soils followed the typical sigmoidal behaviour when a 0.01 M KCl background solution was employed.
In the present study, speciation of aqueous Cu was calculated using measured pH values, aqueous Cu concentrations, DOC concentrations from Eqn 4, and the [Na.sup.+] and O[Ac.sup.-] concentrations in the background solution. Previous work indicated that, due to the strongly leached nature of the podosol A-horizon, the effect of other major ions on aqueous Cu speciation was far less important than those components listed above (Phillips and Burton 2004).
This suggests that the presence of 0.01 M Na+ in the background solution competed with added [Cu.sup.2+] for cation exchange sites, or that a proportion of resident exchangeable cations was not displaced by added [Cu.sup.2+].
defined fraction (mL) 1 'Readily desorbed' Same background solution as 20 used for sorption isotherm method (i.e.
Phosphate sorption curves were obtained using both 0.02 M potassium chloride and 0.01 M calcium chloride as background solutions. For each of at least 7 initial P concentrations, 5 g of soil was mixed with 100 mL of background solution containing the appropriate phosphate concentration.
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