Since MLCT and
LLCT characters of compounds are affected by solvents, the bioactivity measurement procedures, especially the ones that use a light source such as Myoglobin-Assay, must be considered with regard to solvent type.
Frontier orbital analysis shows that this band has the interligand and intraligand ligand-to-ligand charge transfer (
LLCT) characteristics; that is, transitions occur from tpa, edot, and dts groups to edot, dts, and cyanoacrylic acid groups.
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Mixtures of intraligand charge-transfer (ILCT) and ligand-to-ligand charge-transfer (
LLCT) excitations have been correlated to the emission presented by green/emissive Copper (I) compounds based on heteroleptic coumarin (N,N' bidentate)/triphenylphosphine ligands [15].