Caption: Figure 5: ORTEP
view of the 5(3)-trifluoromethyl-4-methyl-3(5)thien-2-yl-1H-pyrazole (5) with the corresponding atom numbers.
Caption: Figure 6: (a) ORTEP
perspective of compound 2.
Crystal structure of the 1st polymorph (1a) and 2nd polymorph (1b) is shown in ORTEP
diagram in Figure 1, respectively.
The perspective view of the molecule and numbering scheme is shown in Fig 2.2 and ORTEP
drawing is shown in Fig 2.3.
views of bis(N,N-dimethyl-N'-4-fluorobenzoylthioureato) nickel(II) (Ni[L.sub.2]) and bis(N,N-dimethyl-N'-4-fluorobenzoylthioureato) copper(II) (Cu[L.sub.2]) with atom numbering schemes are depicted in Figures 4 and 5, respectively.
Table-4: Experimental and theoretical values of selected bond lengths (A) of title compound (atomic labels are in accordance with ORTEP
Caption: Figure 5: Ortep
diagrams of (a) Empp-Ph single crystal and (b) Prmpp-Ph single crystal with ellipsoids, drawn at 50% probability level.
Caption: Figure 2: ORTEP
diagrams of the titled compounds 4c and 7e.
plot benzothiazine derivative is shown in Fig.
diagrams of symmetric dimeric unit, asymmetric unit and close packing diagram of the complex are given in Figs.
The figures were plotted with the aid of ORTEP